Density Fluctuations in an Electrolyte from Generalized Debye-Hückel Theory
نویسندگان
چکیده
منابع مشابه
Density fluctuations in an electrolyte from generalized Debye-Hückel theory.
Near-critical thermodynamics in the hard-sphere (1, 1) electrolyte is well described, at a classical level, by Debye-Hückel (DH) theory with s1, 2d ion pairing and dipolar-pair-ionic-fluid coupling. But DH-based theories do not address density fluctuations. Here density correlations are obtained by functional differentiation of DH theory generalized to nonuniform densities of various species. T...
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ژورنال
عنوان ژورنال: Physical Review Letters
سال: 1996
ISSN: 0031-9007,1079-7114
DOI: 10.1103/physrevlett.76.2906